Practical Electro Chemistry

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With an alloy rich in gold, difficulty is encountered because of the imperfect solubility of the anode and its irregular consumption. Various inventors, notably Borchers and Dietzel, have devised apparatus in which the alloy is granulated and is caused to move relatively to the electrolyte, so that the anode sludge may be separated as it is formed. By these means it is hoped to overcome the obstacles mentioned above, but the processes in question do not appear to have been taken into commercial... use. It is probably preferable so to dilute the refractory alloy, by fusing it with copper or silver as may be necessary, so that it may be regarded as an auriferous copper or an auriferous silver, and may be refined accordingly by electrolysis in a sulphuric acid or nitric acid bath. The difficulties inseparable from the treatment of metal in a granulated state and used as an anode will thus be avoided. Dietzel has worked out a process, which has now been in use for some years by the Allgemeine Gold- und Silber- Scheideanstalt at Pforzheim 117 PEACTICAL ELECTRO-CHEMISTKY which consists in dissolving the gold, silver and copper alloy (about 5 per cent.

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