Practical Organic And Bio Chemistry

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In the non-reducing members the two functional aldehyde or ketone groupings will be combined ; in the reducing members the aldehyde or ketone grouping of the one unit will be united to one of the hydroxyl groups of the other unit. The following are the prob- able formulae for CH 2 OH C (CH. OH)o- CH * CH 2 OH O fructose residue CH (CHOH) 9 > CH CHOH CH 2 OH glucose residue Trehalose ^^-~'0 CHoOH CHOH CH (CHOH) 2 CHx CHoOH CHOH - CH (CHOH) 2 198 PRACTICAL ORGANIC AND BIO-CHEMISTRY Maltose CH. PH... CHOII-CH- (CHOH)^CH-O -CH, CHOH- CH (CHOH) 2 -CHOH cx Lactose Q CH f, OH CH 2 OH- CHOH-CH (CHOH) 2 -CH-O CH-CH- (CHOH) 2 -CHOH galactose residue glucose residue The large number of possible disaccharides may be partly due to the possibility of combination with the several hydroxyl groups and partly to the possibility of the combination of a- or /3- forms of the constituents, thus a a, /3 a, CANE SUGAR.
Cane sugar is very widely distributed in the vegetable kingdom ; 20 per cent, is present in the juice of the sugar cane, 10 to 20 percent, in beetroot ; smaller quantities are present in the maple and birch and sweet fruits contain cane sugar together with glucose and fructose, which are probably derived from it by hydrolysis ; 5 to 1 2 per cent, of cane sugar is present in bananas, apricots, strawberries and pineapple.


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