Practical Physical Chemistry

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Then, knowing the E. M. F. Of the cell and the electrode potential for the calomel electrode, the electrode potential for electrode can be calculated as in previous experiments.
An electrode such as the above, in which the hydrogen is at atmospheric pressure, and normal acid used, is sometimes taken as the standard of potential difference.
The E. M. F. Is 0-277 volt.
Experiment to Determine E. M. F. Of a Hydrogen Concentration Cell Prepare cell H 2 | wHCl | nHCl | HC1 | H'.
Take the same precau
...tions with each electrode as described in previous experiment for the hydrogen electrode. Deter- mine the E. M. F. Every fifteen minutes, until the E. M. F. Is constant.
The E. M. F. In this case is small, so put the cell in series with the Weston cell. Having determined the E. M. F. Of the cell, determine the degree of ionization of hydrochloric acid in normal solution, given that - =0*17 and the degree of ionization for, ~ hydrochloric acid is 0*91.
Extension In a similar manner the student might deter mine the E.


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