Practical Physical Chemistry

Cover Practical Physical Chemistry
Practical Physical Chemistry
Alexander Findlay
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The solutions are then weighed and the amount of silver determined by titration or by electrolytic deposition. If the solution in the second flask does not have the same composition as the original solution, it shows that the experiment has been allowed to continue too long; and it must therefore be repeated, the current this time being stopped after a shorter period.
The method of calculation will be made clear by the following example : Composition of silver solution before electrolysis 9'973
... g m - of water 0*0847 silver nitrate 10*058 solution That is, for every 9^973 gm. Of water there are 0*0847 gm. Of silver nitrate or 0*000498 gm. Equivalents of silver. A current of about 6-7 milliamperes was passed through the solution for about 2\ hours.
After electrolysis, the solution had the composition 1 The current should be passed until about 0^05 to OT gm. Of copper is deposited in the voltameter.
1 86 PRACTICAL PHYSICAL CHEMISTRY 2676 gm. Of water 0-2818 silver nitrate 27*04 solution.


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