Principles of Inorganic Chemistry

Cover Principles of Inorganic Chemistry
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It differs, however, from sulphurous acid in not being a strong reducing agent. Indeed, it is not a reducing agent at all, but readily gives up its oxygen, and is therefore an oxidizing agent. When selenious acid is treated with sulphur dioxide, the former is reduced to selenium, and the latter oxidized to sulphuric acid.
While the compound selenium trioxide is not known, the acid corresponding to this anhydride is known. When selenium is treated with strong oxidizing agents, such as chlorine o
...r bromine water, or metallic selenites treated with bromine or fused with potassium nitrate, selenic add or its salt is formed. The acid is a solid, melting at 58. Like sulphuric acid it combines with water, forming a hydrate, H 2 Se0 4 . H 2 0. Unlike sulphuric acid it is a strong oxidizing agent, readily giving up its oxygen and passing over to selenious acid or selenium.
Selenium combines with chlorine, forming two chlorides ; selenium monochloride, Se 2 Cl 2, and selenium tetrachloride, SeCl 4 .


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