Proceedings of the American Academy of Arts And Sciences
Proceedings of the American Academy of Arts And Sciences
Boston: Published By the Academy
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Chem., 12, 116 (1875). Digitized by Google 236 JONES AND SCHUMB. 0.05 N and 0.02 N potassium iodide, saturated with iodine^ measured against the decinormal calomel electrode at 26** and (f with the following results (uncorrected for liquid junctions): 25* 0* Pt, lasat., 0.1NKI,0.1NKCl,HgaCl2,Hg; E = -0.2804V. -0.2753v. Pt, la sat., 0.05 N KI, 0.1 N KCl, HgjCU, Hg; E = -0.2976 -0.2909 Pt, I, sat., 0.02 N KI, 0.1 N KCl, HgjCl,, Hg; E = -0.3200 -0.3114 From these results the normal potential of th...e iodine electrode is computed to be: 25** 0* Pt, 1 molal 1,, 1. N I- 1.0 N KCl, HgiCl,, Hg; E = -0.3406v. -0.3899v. 6. From the foregoing results the following results are compated for the reaction: Tl (solid) + 1/2 la (solid) = Til (solid): 25* 0* Free Energy of Formation (A) 125.79 kj. 125.4Sk]. Heat of Formation (U) 122.11 kj. This investigation has been aided by a grant from the Cyrus M. Warren Fund of the American Academy of Arts and Sdences, far which we wish to express our appreciation. Harvard University, Cambridge, Mass.
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