Proteins And the Theory of Colloidal Behavior

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(For the sake of simplification complete electrolytic dissociation of HC1 and gelatin chloride is assumed. ) Since all the quantities in Equa- tion (1) are positive, the concentration x of the hydrogen ions in the outside solution must be greater than the concentration y of the hydrogen ions in the inside solution; and the total con- centration of the chlorine ions in the inside solution, y + z, must be greater than the concentration of the Cl ions in the out- side solution, x. This difference ...in the distribution of the crystalloidal ions on the opposite sides of the membrane is caused by the fact that one type of ions (the protein ions) cannot diffuse through the membrane.
We now come to the most important point for the foundation of the theory of colloidal behavior. If it is true that the Donnan equilibrium is the cause of the P. D. Between a gelatin chloride solution and the outside solution, the Donnan equilibrium is likely to be also the cause of the influence of the mysterious influence of electrolytes on the other properties of proteins, since the curves for P.


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