Qualitative Analysis ; Quantitative Analysis

Cover Qualitative Analysis ; Quantitative Analysis
Qualitative Analysis ; Quantitative Analysis
International Correspondence Schools
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The color is due to the formation of red, soluble ferric sulphocyanide, Fe{SCN)^, Digitized by Google 64 QUALITATIVE ANALYSIS § 20 The color is not injured by hydrochloric acid, but is destroyed by mercuric chloride.
6. When a sulphocyanide is heated with nitric acid, a violent decomposition takes place, during which nitric and carbonic oxides are given off, and sulphuric acid is formed.
HYDROFERROCYANIC ACTD 48. Hydroferrocyanic acid, HJ^e{CN)^y is a colorless, crystalline substance that readi
...ly dissolves in water, giving a liquid with a strong acid reaction. The ferrocyanides of the alkalies and alkaline earths are soluble, while most of the others are insoluble in water. They are all decomposed by ignition in the closed tube, and if they are not quite dry, hydrocyanic acid, carbon dioxide, and ammonia are given off.
If perfectly dry, nitrogen, and sometimes cyanogen, escape.
1. Silver nitrate precipitates white silver ferrocyanide, Ag^Fe{CN)^, which is insoluble in nitric acid, and in ammo- nia in the cold, but is dissolved by potassium cyanide.


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