Quantitative Analysis

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The quantitative conversion of sodium carbonate into sodium bicarbonate by means of an acid can take place only when care is 228 QUANTITATIVE ANALYSIS taken to prevent the escape of carbon dioxide. At the point where the acid enters the solution there is at first complete con- version of a part of the carbonate into the normal sodium salt of the added acid. If carbon dioxide escapes from the solution at this point more acid will be required to produce the first end point than would otherwise be
... the case. The escape of gas may be prevented by keeping the solution at a temperature near and by adding the standard acid very slowly and while stirring vigorously. 1 It is very difficult to avoid the escape of carbonic acid unless the relative amount of carbonate is small. On this account the method is best suited to bases, in which carbonate occurs as an impurity, rather than to materials in which carbonate is an essential constituent.
Determination of Hydroxide and Carbonate in Commercial "Caustic Soda" or "Caustic Potash.


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