Quantitative Chemical Analysis volume 1

Cover Quantitative Chemical Analysis volume 1
Quantitative Chemical Analysis volume 1
C Remigius Fresenius
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Ilydrated Fluorides. A sample of the substance is heated in a tube. aa. The Water expelled does not redden Litmus Paper. The water is determined by ignition ; the fluorine and metal as directed in <7, a. bb. The Water expelled has an acid reaction. The substance is treated with sulphuric acid as directed in #, a, to determine the metal, on the one hand, and the water -|- fluorine on the other. Another weighed portion is then mixed, in a small retort, with about 6 parts of recently ignited lead oxide ; the mixture is covered with a layer of lead oxide, the retort weighed, and the water expelled by the application of heat, increased gradually to redness. No hydrofluoric acid escapes in this process. The weight of the expelled water is inferred from the loss. The first operation having given us the water -|- fluorine, and the second the water alone, the dif- ference is consequently the fluorine. I). Decomposition by Fusion with Alkali Carbonates. Many insoluble fluorides, aluminium fluoride for instance, may 138.

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