Quantum Theory of Chemical Reaction Rates
Quantum Theory of Chemical Reaction Rates
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)> i. E. , for each initial and final state of rotation in the p-coordinate. Thus there will be a corresponding change in the condition for conservation of energy, (15), in that e^ = ^n^^n"^n^' where v and J are respectively vibra- tional and rotational quantum numbers.
N. 12 Ihis section was written as a result of some remarks by Dr. S. H. Bauer.
- 20 - (iii) Precisely which transitions J -j„ are possible depends on the form of V. (p), and more particixlar3y on V'(p, i^). If V. Is independent ...of a, p, the polar coordinates in the p- coordinates, vre have, (30) 0Jp) = 0^(p) Yj^Ja, p); where Y. Are normalized spherical harmonics. Then if V is independent of (a, p), j^ = j^; if V ru cos a, J^ = Jf ± 1. Etc.
(iv) Overall, the effect of molecular rotation on the vibrational motion will be the addition of rotational fine structure to the energy level diagrams . However, this does not invalidate any of the present arguments regarding the character and magnitude of quantum jumps, because of the selection rules that will be enforced by a 'reasonable' form of V.
What to read after Quantum Theory of Chemical Reaction Rates?
You can find similar books in the "Read Also" column, or choose other free books by Ernest Bauer to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
)> i. E. , for each initial and final state of rotation in the p-coordinate. Thus there will be a corresponding change in the condition for conservation of energy, (15), in that e^ = ^n^^n"^n^' where v and J are respectively vibra- tional and rotational quantum numbers.
N. 12 Ihis section was written as a result of some remarks by Dr. S. H. Bauer.
- 20 - (iii) Precisely which transitions J -j„ are possible depends on the form of V. (p), and more particixlar3y on V'(p, i^). If V. Is independent ...of a, p, the polar coordinates in the p- coordinates, vre have, (30) 0Jp) = 0^(p) Yj^Ja, p); where Y. Are normalized spherical harmonics. Then if V is independent of (a, p), j^ = j^; if V ru cos a, J^ = Jf ± 1. Etc.
(iv) Overall, the effect of molecular rotation on the vibrational motion will be the addition of rotational fine structure to the energy level diagrams . However, this does not invalidate any of the present arguments regarding the character and magnitude of quantum jumps, because of the selection rules that will be enforced by a 'reasonable' form of V.
What to read after Quantum Theory of Chemical Reaction Rates?
You can find similar books in the "Read Also" column, or choose other free books by Ernest Bauer to read onlineMoreLess
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