Researches On Cellulose Iii 1905 1910

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The complete destruction of the characteristic constituent groups of the lignone complex under such oxidations as we are considering, relegates them to another constitutional class.
In some recent researches towards a closer definition of the constitutional relationships of the ' acetic residues ' of the lignone complex ('Cellulose, ' 1905, p. 191), we have made quantitative determinations of the simpler products of those oxidations under the conditions of interaction as under : Jute fibre 100
...; CrO 3 42 ; water 1900; H 2 SO 4 100 total volume 2000 c. C. At i6C. ; digested forty-eight hours. The yield of fibrous residue (' oxycellulose ') was 79 p. Ct. ; the net loss of the ligno-cellulose therefore 2 1 p. Ct.
Acetic Acid. The total volatile acid, originally distilled from the solution and calculated as acetic acid, was 6*0 p. Ct. Of the ligno-cellulose.
A second fraction of the solution was treated with CrO 3 in excess, digested for some hours at 90-100 and then distilled. The volatile acid was reduced to 5*2 p.


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