Short Introduction to the Theory of Electrolytic Dissociation

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20. Acids, Alkalies and the Hydrogen and Hydroxyl Ions. Soluble chlorides have the common property of precipitating silver chloride from silver solutions, because they have the common ion CF. Acids are dissociated electrolytically in solution, as indicated by their being electrolytes and by their abnormally depressing the freezing point. Their common properties must therefore be referred to their common ion. The acidity of hydrogen chloride indicates that this common ion is that of hydrogen. Th
...e chlorine ion certainly does not confer acid pro- perties on its solution, and there only remains the hydrogen ion. All acids are known to contain hydrogen, and an investigation of the reactions into which they enter, confirms the belief that they are characterised by their hydrogen ions when in solu- tion. This confirmation is the more complete, inas- much as not only can the reactions of acids be shown to be connected with the presence of hydrogen ions, but their strengths are found to be proportional to the extent of their dissociation.

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