Significance of the "protection Potential" for Fe-Cr Alloys At Room Temperature.
Significance of the "protection Potential" for Fe-Cr Alloys At Room Temperature.
Starr, Kenneth Kirch, 1944-
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2.7.2 Experimental Methods An electrochemical hysteresis technique [153, 154] (a cyclic 55 potentiokinetic method), developed by Pourbaix et al. [52, 49, 3] has been the usual method used for determining "protection potentials." Details of this method will be given in Chapter 3. Szklarska-Smialowska and Janik-Czachor [50] discussed various potentiostatic, potentiokinetic, galvanostatic and galvanokinetic methods for the determination of characteristic pitting potentials. The characteristic pitt...ing potentials were a critical potential for pit initiation (rupture potential) and a critical potential for pit propagation ("protection potential"). Up to the present time the experimental work has primarily been done on iron-rich alloys (Fe [129, 27], Fe-Cr [54, 55, 153, 154] and stainless steel [52, 49, 3, 88, 155]), copper-rich alloys (Cu [149, 150, 156], Cu-Ni [157, 156] and Cu-Zn [158, 159, 160]) and nickel-rich alloys (Ni-Cu [156]). 2.7.3 Interpretation of the "Protection Potential" for Cu-Rich Alloys One result of the research mentioned above was that the "protection potential" for copper and copper-rich alloys was observed to be relatively pH-independent [157, 158, 159, 160, 156] and approximately equal to +0.200 v CUI?
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