Smaller Chemical Analysis
Smaller Chemical Analysis
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H 2 S only produces complete precipitation of NiS from a warm solution of the acetate, or from other nickel salts in the presence of an alkaline acetate. In the case of neutral solutions of nickel salts with mineral acids, the precipitation is only partial, while in acid solutions it does not take place at all. KCy gives a pale-green precipitate of nickelous cyanide, 48 Smaller Chemical Analysis NiCy 2, readily soluble in excess of the reagent forming the double cyanide, K 2 NiCy 4 . From this ...solution (NH 4 ) 2 S fails to precipitate the sulphide. Dilute mineral acids cause the reprecipitation of nickelous cyanide K 2 NiCy 4 + 2HC1 = 2 KC1 + 2HCy + NiCy 2 Boiling with hydrochloric acid decomposes the metallic cyanide altogether K 2 NiCy 4 + 4HC1 = 2KC1 + 4HCy + NiCl 2 Oxidising agents, such as hypochlorites, chlorine, or bromine precipitate the black hydrated sesquioxide. (Distinction from cobalt. } 2 K 2 NiCy 4 + NaCIO + 5H 2 O = Ni 2 O 3, 3H 2 O + NaCl + 4 KCy Cobalt, Co DRY REACTIONS.
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You can find similar books in the "Read Also" column, or choose other free books by George S Newth to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
H 2 S only produces complete precipitation of NiS from a warm solution of the acetate, or from other nickel salts in the presence of an alkaline acetate. In the case of neutral solutions of nickel salts with mineral acids, the precipitation is only partial, while in acid solutions it does not take place at all. KCy gives a pale-green precipitate of nickelous cyanide, 48 Smaller Chemical Analysis NiCy 2, readily soluble in excess of the reagent forming the double cyanide, K 2 NiCy 4 . From this ...solution (NH 4 ) 2 S fails to precipitate the sulphide. Dilute mineral acids cause the reprecipitation of nickelous cyanide K 2 NiCy 4 + 2HC1 = 2 KC1 + 2HCy + NiCy 2 Boiling with hydrochloric acid decomposes the metallic cyanide altogether K 2 NiCy 4 + 4HC1 = 2KC1 + 4HCy + NiCl 2 Oxidising agents, such as hypochlorites, chlorine, or bromine precipitate the black hydrated sesquioxide. (Distinction from cobalt. } 2 K 2 NiCy 4 + NaCIO + 5H 2 O = Ni 2 O 3, 3H 2 O + NaCl + 4 KCy Cobalt, Co DRY REACTIONS.
What to read after Smaller Chemical Analysis?
You can find similar books in the "Read Also" column, or choose other free books by George S Newth to read onlineMoreLess
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