Studies From the Rockefeller Institute for Medical Research, volume 32
Studies From the Rockefeller Institute for Medical Research, volume 32
Rockefeller Institute for Medical Research, Rockefeller Institute
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Since at the isoelectric point gelatin (and probably amphoteric colloids generally) must give oflE any ion with which it was com- bined, the simplest method of obtaining amphoteric colloids approxi- mately free from ionogenic impurities would seem to consist in bring- ing them to the hydrogen ion concentration characteristic of their isoelectric point (i.e., at which they migrate neither to the cathode nor anode of an electric field). 3. It is shown by volimietric analysis that when gelatin is ...in com- bination with a monovalent ion (Ag, Br, CNS), the curve representing the amount of ion-gelatin formed is approximately parallel to the curve for swelling, osmotic pressure, and viscosity. This fact proves that the influence of ions upon these properties is determined by the chemical or stoichiometrical and not by the "colloidal" condition of gelatin. 4. The sharp drop of these curves at the isoelectric point finds its explanation in an equal drop of the water solubility of pure gelatin, which is proved by the formation of a precipitate.
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