Studies in Catalysis

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Studies in Catalysis
James Mcintosh Johnson
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" J. Chem. Soc. , 85, 1098. Ber. D. Chem. Ges. , 34, 4115.
14 Z. Physik. Chem.. 5, 1; 13, 407.
Ibid. , 4, 319; 32. 137; J. Chem. Soc. , 77, 5.
w Z. Physik. Chem. , 12, 167.
4 6 in which, C 5ub is the original concentration of the base in gram molecules per liter, oc the amount of base transformed into the other products at any moment, (C sub x) the concen- tration of the base at any moment, C H that of the hydrogen ions, C saltdis that of the dissociated portion of the salt, practically all ion
...ized, K hyd the hydrolysis constant, K b the affinity constant of the base and K w the ion product for water at the given temperature. But the amount of salt, C salidis, present in such cases is extremely small and for (C sub x) and Cff we may substitute, without appreciable error, the values they would have if no salt were formed. In those cases in which C saltdis is large this cannot be done, but the concentrations of each substance can be determined from (i).
It is the opinion of a large number of chemists that the above salts are intermediate compounds in the catalytic trans- formations spoken of, and that such catalytic reactions are brought about solely because of, and through, the formation of such intermediate compounds.


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