Studies in Time-Resolved Optoacoustic Spectroscopy
Studies in Time-Resolved Optoacoustic Spectroscopy
Voigtman, Edward George
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76 Among the disadvantages of using biacetyl for TROAS studies are its reactivity, low S Q -^ T-, oscillator strength (1.4 x 10" 7 [87]), and foul odor (rancid butter). On the whole, the advantages probably outweigh the disadvantages insofar as TROAS is concerned. CHAPTER FIVE EXPERIMENTAL ARRANGEMENTS The major components of the attempted TROAS experiments are presented (in concise form) in rough chronological order in Table 8. The arrangement of the components was essentially that of Figure 2... though, of course, the initial experiments were performed without the aid of either microcomputer system or transient waveform recorder. Consequently, the complexity of the experimental apparatus increased (as necessary) to obtain results and eliminate interferences. The previous experiments had been performed in the near-UV (320- 420 nm) where the performance of the Phase-R DL-1200 coaxial flashlamp- pumped dye laser was yery poor, at best [47]. It was decided, therefore, to use this system in the visible region only, where dye performance is much better and alignment of the system is far easier.
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