Studies On the Silver Coulometer

Cover Studies On the Silver Coulometer
Studies On the Silver Coulometer
Garrett Davis Buckner
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59848 +0. 93 4-1. 90 IO 4. 97976 4. 98037 4. 98184 -fo. 6i +2. 08 II 6. 26538 6. 26596 6. 26661 +0. 58 +1. 23 If we calculate the percentage difference in the weight of silver deposited on platinum and on gold by the same current, we find that the deposits on the gold are 0. 012 0. 0012 percent heavier than the deposits on platinum, while in the Rayleigh coulometer, where Kahlbaum's C. P. Silver nitrate and the filter paper enclosed anode were used, we found the deposits to be 0. 030 . 0. 0033 ...percent heavier than the deposits made on the normal platinum cathode cup. In every case it was found that the silver 10 G. D. BUCKNER.
deposited on gold was heavier than that deposited on platinum by the same current, the average excess being 12 parts in 100, 000. This could be explained by assuming that part of the current in the platinum coulometers passed from the catholyte to the plat- inum cathode by removing oxygen from the platinum.
The silver samples reserved from these runs were investigated by Mr.


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