T N T; Trinitrotoluenes And Mono- And Dinitrotoluenes, Their Manufacture And Properties

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E. Bichtel (12) has analyzed the gases from TNT under several conditions of explosion. From the com- plete explosion of the material under atmospheric pressure the gas gave the following analysis: Per Cent.
Carbon monoxide 70 . 5 Carbon dioxide 3.7 Hydrogen 1.7 Nitrogen 19.9 Carbon 4.2 Under pressure, the explosion of TNT gives a dif- ferent gas, including methane and considerably more hydrogen : PROPERTIES OF THE TRINITROTOLUENES 91 Per Cent.
Carbon monoxide 59.01 Carbon dioxide 1 . 93 Methane
... 1 .97 Hydrogen 21 .05 Nitrogen 16.05 The gases from the explosion of TNT in a lead block (from Trauzl test) upon partial analysis gave these figures : Per Cent.
Carbon dioxide 20.60 Carbon monoxide 46 . 02 Methane 1.40 Hydrogen 7.61 Hydrocarbons 1 .08 Some authorities state that in all probability gases of entirely different constitution exist at the moment of detonation than after bemg cooled for analysis. The formation of methane and carbon dioxide may be due to the heat of the gases at the moment succeeding the explosion, at which moment the gases may, due to the heat, be dissociated.


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