Testing for Metallurgical Processes

Cover Testing for Metallurgical Processes
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This very simple, though delicate, process depends upon the fact that the silver in cop- per mattes is converted into silver sulphate by means of the sulphuric anhydride evolved from the decom- position of iron sulphate and copper sulphate, which are formed during the roasting from the iron and copper sulphides present in the mattes. The pro- cess consists of roasting the sulphides with an ex- cess of air, so that they are oxidized partly to sul- phates, which are then heated sufficiently to de...com- pose the sulphates of iron and most of the sulphates of copper, while the silver remains sulphatized as AgS0 4 and may be dissolved out with boiling water to be subsequently precipitated on metallic copper. Simple as it appears this process is extremely diffi- cult to execute, for it requires a high degree of skill to seize the exact period when the iron and copper sulphates are converted into their insoluble higher oxides and when none of the silver sulphate is de- composed.
Procedure. Grind about 1% lb.


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