The Absorption Spectra of Solutions of Comparatively Rare Salts Including Those
The Absorption Spectra of Solutions of Comparatively Rare Salts Including Those
Harry Clary Jones
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" Ibid. , 29. MAPPING ABSORPTION SPECTRA OF VARIOUS SALTS. 33 In strip 1, B, plate 2, cd is 6 and the middle of the edge of absorption is at about X 4150, the edge of the band being about 300 Angstrom units wide. The edge of the absorption is very wide and diffuse, resembling the absorption of potassium ferrocyanide. No direct comparison of the absorption in the two cases can be made, as the value of cd is much larger in the case of the calcium salt. THE CHROMATE AND BICHROMATE OF LITHIUM. The ...absorption spectrum of an aqueous solution of lithium chromate is given in A, plate 1, and of lithium bichromate in B, plate 1. In the case of lithium chromate a change in cd of 0. 75 to 6. 0 produces an increase in width of the absorption of over 200 Angstrom units; the edge of the band being at about X 4850 for cd = 0. 75. This is approximately the position of the edge of the absorption band of potassium chromate for a corresponding value of cd. For lithium bichromate, the edge of the absorption for strip 1, cd = 0.
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