The Action of Various Anhydrous Chlorides On Tellurium Trioxide

Cover The Action of Various Anhydrous Chlorides On Tellurium Trioxide
The Action of Various Anhydrous Chlorides On Tellurium Trioxide
Snyder, Andrew Joseph
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The preci- pitates after v/eighing were dissolved and reprecipitr.ted in order to check the first wei^^hings.
4 Te 47.21 CI 52.79 50.10 51.05 49.69 50.86 50.53 49.24 Digitized by Google Digitized by Google -8- Antimony Pentachloride^ Tellurium trioxide is not acted upon by antimony penta- chloride at room temperature or when heated to 100^. When heated to 175^ for seven hours all the tellurium trioxide went into solution v/ith the formation of syrup-like liquid* The viscosity increased with the
... amount of telluritim trioxide in solution. It was impossible to get any crystals by heating.
The tubes were then chilled in a freezing mixture for tiiree days when large flat crystals appeared. These crystals were permanent at room temperature .Crystals were not obtained when only a small amount of tellurium trioxide was present.
Very little gas was given off when these tubes were opened, The odor of chlorine was noticed in several instances.
On washing the crystals with carbon bisulphide, a reddish appearance was given to them, which changed to a greyish yellow when dry.


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