The Analytical Chemist's Assistant: a Manual of Chemical Analysis, Both Qualitative And Quantitative of Natural And Artificial Inorganic Compounds, to Which Are Appended the Rules for Detecting Arsenic in a Case of Poisoning

Cover The Analytical Chemist's Assistant: a Manual of Chemical Analysis, Both Qualitative And Quantitative of Natural And Artificial Inorganic Compounds, to Which Are Appended the Rules for Detecting Arsenic in a Case of Poisoning
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The quantity of the evolved centigrammes of carbonic acid, divided by two, gives the amount of carbonate of potassa in the potash, for 3.14 grm.
of pure carbonate of potash produce 1.00 grm.
carbonic acid. For the sake of greater accuracy we take the double amount, equal to 6.28.
b. Soda. — We take 4.82 grm. of the anhydrous compound, that is twice 2.41, which is the quantity of pure carbonate of soda, from which the acid evolves 1.00 grm. of carbonic acid.
If a soda contain caustic soda, known
... from the fact that, after adding an excess of chloride of barium, the solution is alkaline in its reactions, we proceed in the following manner.
4.82 grm. of the anhydrous compound are rubbed up with three parts of pure quartz sand and about one-third of pulverized carbonate of ammonia, moistened with water, and after some time slightly heated to drive off all the water and ammonia.
On cooling, the whole mass is placed in the evolving apparatus, and treated as above.
APPENDIX.
MODE OF DETECTING ARSENIC IN A CASE OF POISONING.


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