The Chemical Synthesis of Vital Products And the Interrelations Between Organic

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The Chemical Synthesis of Vital Products And the Interrelations Between Organic
Raphael Meldola
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] Ettxanthone [136] gives quinol among the products of fusion with potash (Baeyer, Zeit. [2j 5, 569).
[N. ] Succinic acid [Vol. II] gives quinol among other products by the dry distillation of its salts (v. Richter, Journ. Pr. Ch. [2] 20, 207).
Or succinic acid (ester) by the action of sodium in presence of alcohol or of dry sodium ethoxide can be converted into succinylsuccinic (cyclohexanedione- 2 : 5-dicarboxylic- 1 : 4) ester (Fehling, Ann. 49, 186 ; Herrmann, Ber. 10, 107 ; Ann. 211, 306 ;
... Duisberg, Ber. 16, 133 ; Volhard, Ibid. J 34 ; Piutti, Gazz. 20, 167; Vorlander, Ann. 28O, 186). The latter on oxidation by air or bromine gives p-dihydroxyterephthalic (quinol- dicarboxylic or 2 : 5-phenedioldicarboxy- lic) ester (Herrmann, loc. Cit. 1 1 1 ; Ann. 211, 327), and the acid on dry distilla- tion or on fusion with potash yields quinol (Ibid. Ber. 10, 1 1 2 ; Ann. 211, 33 6 )- Or succinylsuccinic ester can be con- verted into dihydroxyterephthalic acid by the action of phosphorus pentachloride (Levy and Curchod, Ber.

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