The Chemistry And Technology of Gelatin And Glue

Cover The Chemistry And Technology of Gelatin And Glue
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56, the small scale graph, the curve takes a new and sharply downward direction indicating the final solid phase of Ca(H 2 P04)2. H 2 O which probably persists as long as any solid is present.
The precipitation of calcium phosphate of any definite analysis may be accomplished by addition of lime until the analysis of the liquor corresponds to that of the liquor in equilibrium with solid of the desired composition on the graph. This is desirable because a routine gravimetric analysis of the soli
...d phase requires considerable time while a titration of the liquor may be obtained in about 10 minutes. Also if the calculated amount of lime is added and by accident the desired point is passed, the addition of liquor according to a new calculation for correction does not produce a precipitate as citrate-soluble as that resulting when no over-reaching has occurred.
The preferable procedure is to slowly add milk of lime while stirring thoroughly until 90 or 95 per cent of the desired amount is added, then to allow the mixture to stand over night to come to equilibrium.


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