The Chemistry of Colloids And Some Technical Applications
The Chemistry of Colloids And Some Technical Applications
W W William White Taylor
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Gelatine with alcohol or benzene as dis- persion medium forms series of gels which have been examined by Bachmann. 1 Alcogels and benzogels of gelatine show apart from certain special features which arise from the mechanical properties of their structure a marked similarity in the course and hysteresis-cycle of their vapour pressure isotherms with those of silicic acid hydrogel, and others. The common cause is the similarity of the processes involved the reduction of vapour pressure of the imbi...bed liquid owing to the action of capillarity in an amicroscopic hollow-spaced system. The same cycle of events must always occur with a liquid and a porous substance with capillary spaces and walls of adequate resistance, provided no secondary changes, such as chemical reactions, occur. By applying the theory of capillarity, it is possible to estimate approximately the size of the spaces ; they are 30-100 times smaller than Biitschli's network, i. E. 2-30 juju in diameter. Elastic Gels The differences in the hydration phenomena of elastic gels, of which gelatine or agar may be taken as the type, and the non-elastic gels are sufficiently great to warrant their separation, although they have much in common, and the groups merge into each other.
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