The Chemistry of Linseed Oil

Cover The Chemistry of Linseed Oil
The Chemistry of Linseed Oil
J Newton John Newton Friend
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25 26 The presence of other oils does not hinder the reaction. For example, if linseed oil is mixed with olive oil, which latter yields no pre- cipitated bromides, the same quantity of precipitate is obtained as if the linseed oil were brominated alone.
The following amounts of precipitated bromides have been obtained by different investigators with various oils : Oil.
Per cent. Bromides.
Linseed (Hehner and Mitchell 25 ) . Do. (Ingle 26 ) 23-86-25-8 33'7 -48-1 Do. (Sutcliffe 27 ) Hempseed (Spr
...inkmeyer and Diedrichs M ) . Walnut* 1 ... . .
41-6 -49-3 8-82 1 '42-1 '9 Do. 28 Tung 25 Cotton-seed 25 2-22 nil nil Olive 25 nil 42 PROPERTIES AND REACTIONS If the weight of precipitated bromides obtained from a given sample of linseed oil falls below 20, adulteration may fairly safely be affirmed.
The interaction of bromine and the oil results in the evolution of heat, and the rise in temperature bears some relation to the extent of unsaturation of the organic acid radicles. It is commonly known as the heat of bromination or the bromine thermal value, this latter term being preferable for the reason given below.


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