The Conductivity of Liquids; Methods, Results, Chemical Applications And Theoretical Considerations
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REDUCTION OF CONDUCTIVITY MEASUREMENTS FOR SMALL TEMPERATURE DIFFERENCES. — When only a few conductivity measurements are to be made, in order to save time required to adjust a temperature bath at 18°, the measurements may be made at room temperature, care being exercised to take the temperature of the solution at the instant when the measurements are made.
Subsequently, the results can be reduced to 18° by means of the coefficients given on page 99. If the temperature interval is slight the te...mperature coefficient c can be employed alone without sensi- ble error.
1 That is, recombination of the ions at these temperatures absorbs heat.
2 See Eversheim : Drud. Ann., 8, 560 (1902) ; Walden and Centnerszwer: Ztschr.
hys. Chem., 39, 538 (1902), and also discussion in Chapter 12.
I02 THE CONDUCTIVITY OP LIQUIDS For example, a tenth-normal solution of silver nitrate gave K = 0.00793 at 19.32°. The temperature coefficient c of silver nitrate in the table is in round numbers 0.022. Since the differ- ence of temperature here is only 1.32°, the use of this approximate coefficient will cause no appreciable error.
What to read after The Conductivity of Liquids; Methods, Results, Chemical Applications And Theoretical Considerations?
You can find similar books in the "Read Also" column, or choose other free books by Olin Freeman Tower to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
REDUCTION OF CONDUCTIVITY MEASUREMENTS FOR SMALL TEMPERATURE DIFFERENCES. — When only a few conductivity measurements are to be made, in order to save time required to adjust a temperature bath at 18°, the measurements may be made at room temperature, care being exercised to take the temperature of the solution at the instant when the measurements are made.
Subsequently, the results can be reduced to 18° by means of the coefficients given on page 99. If the temperature interval is slight the te...mperature coefficient c can be employed alone without sensi- ble error.
1 That is, recombination of the ions at these temperatures absorbs heat.
2 See Eversheim : Drud. Ann., 8, 560 (1902) ; Walden and Centnerszwer: Ztschr.
hys. Chem., 39, 538 (1902), and also discussion in Chapter 12.
I02 THE CONDUCTIVITY OP LIQUIDS For example, a tenth-normal solution of silver nitrate gave K = 0.00793 at 19.32°. The temperature coefficient c of silver nitrate in the table is in round numbers 0.022. Since the differ- ence of temperature here is only 1.32°, the use of this approximate coefficient will cause no appreciable error.
What to read after The Conductivity of Liquids; Methods, Results, Chemical Applications And Theoretical Considerations?
You can find similar books in the "Read Also" column, or choose other free books by Olin Freeman Tower to read onlineMoreLess
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