The Constitution of the Natural Silicates

Cover The Constitution of the Natural Silicates
The Constitution of the Natural Silicates
Frank Wigglesworth Clarke
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The latter considera- tion applies throughout the discussion.
At the other end of the series we have the magnesian tourmaline from Pierrepont, New York, as analyzed by Riggs. The mixed molecules are nearly as follows : Al S iO 4 =FeH I Si0 4 E=FeH \Si0 4 Al B0 2 3 Al BO 3 =NaH x Si0 4 =Al-B0 2 Al SiO 4 =FeH \SiO 4 EEEFeH + / Si0 4 =MgH Al Si0 4 =MgH \Si0 4 =Al B0 2 2 Al BO 3 =NaH /SiO 4 = Al BO 2 Al Si0 4 =MgH /SiO 4 =MgH Al SiO 4 =MgH \Si0 4 =Al B0 2 5 Al BO 3 =Ca /SiO 4 = Al BO 2 Al Si0 4 =Mg
...H \Si0 4 =MgH Found.
Calculated.
SiO 2 35. 61 35. 91 Ti0 2 55 B 2 O, 10. 15 10. 48 ALOo 25. 29 25. 44 FeoOo . 44 FeO 8. 19 8. 62 MffO 11. 07 11. 17 Ca g O 3. 31 2. 79 NaoO.
1. 51 1. 55 K 2 O . 20 H 2 O 3. 34 4. 04 F . 27 v 99. 93 100. 00 An interesting intermediate tourmaline is the black variety from Lost Valley, California, analyzed by Schaller. Its formula is that of a mixed crystal, as follows : Al SiO 4 ==Al \SiO 4 =Al BO, 2A1 B0 3 =Na 2 + 2 Al BO 3 = I I /oi0 4 Al BO 2 >SiO^=Al- Al SiO 4 =Al \Si0 4 =Al /Si0 4 = Al ^ S iO=FeH Al-SiO=MgH \Si0 4 =Al-B0 2 \Si0 4 =Al-B0 2 1 Al B0 3 =H 2 Si0 4 =Al B0 2 Al Si0 4 =MgH \Si0 4 =MgH Al Si0 4 =FeH 70 THE CONSTITUTION OF THE NATURAL SILICATES.


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