The Determination of Hydrogen Ions; An Elementary Treatise On the Hydrogen Electrode, Indicator And Supplementary Methods, With An Indexed Bibliography On Applications
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To quickly assess the difficulty of the text, read a short excerpt:
In S0rensen's work, published prior to the adoption of the pres- ent standard value of the Weston standard cell, the basis for the particular cell whose value he gave was not stated. If it was the 1.01863 used in Germany prior to 1911 the correction of S0ren- sen's data to the present international volt will not be significant.
Doubtless the international standard was used in Denmark when STANDARDIZATION OF pH MEASUREMENTS 197 S0rensen (1912) published the summary of the data of S0rensen and Ko...efoed. Their values involve two assumptions; first that liquid junction potential differences were eliminated by the Bjer- rum extrapolation; second, that in the calculation of the theoreti- cal difference of potential between the normal hydrogen electrode and the hydrogen electrode in the hydrochloric acid solutions used, the correct hydrogen ion concentration was given by con- ductance data. As already stated there is serious doubt of the validity of the last assumption. Even so we ought, by using the same degree of dissociation for hydrochloric acid solutions, to reconcile S0rensen's value with that of Lewis, Brighton and Se- bastian.
What to read after The Determination of Hydrogen Ions; An Elementary Treatise On the Hydrogen Electrode, Indicator And Supplementary Methods, With An Indexed Bibliography On Applications?
You can find similar books in the "Read Also" column, or choose other free books by W Mansfield William Mansfield Clark to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
In S0rensen's work, published prior to the adoption of the pres- ent standard value of the Weston standard cell, the basis for the particular cell whose value he gave was not stated. If it was the 1.01863 used in Germany prior to 1911 the correction of S0ren- sen's data to the present international volt will not be significant.
Doubtless the international standard was used in Denmark when STANDARDIZATION OF pH MEASUREMENTS 197 S0rensen (1912) published the summary of the data of S0rensen and Ko...efoed. Their values involve two assumptions; first that liquid junction potential differences were eliminated by the Bjer- rum extrapolation; second, that in the calculation of the theoreti- cal difference of potential between the normal hydrogen electrode and the hydrogen electrode in the hydrochloric acid solutions used, the correct hydrogen ion concentration was given by con- ductance data. As already stated there is serious doubt of the validity of the last assumption. Even so we ought, by using the same degree of dissociation for hydrochloric acid solutions, to reconcile S0rensen's value with that of Lewis, Brighton and Se- bastian.
What to read after The Determination of Hydrogen Ions; An Elementary Treatise On the Hydrogen Electrode, Indicator And Supplementary Methods, With An Indexed Bibliography On Applications?
You can find similar books in the "Read Also" column, or choose other free books by W Mansfield William Mansfield Clark to read onlineMoreLess
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