The Dynamical Theory of Gases Microform
The Dynamical Theory of Gases Microform
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It is, however, quite clear from experiment that for many gases the value of 7 is very much lower than 1^. In other words, the molecules of many substances must not be regarded simply as rigid bodies, for the energy of internal motion is comparable with the energies of translation and rotation.
272. Various attempts have been made to connect the values of n and 7 with the number of atoms in the molecule. Naumann*, for instance, suggested that n is identical with the number of atoms in the molec...ule, while J. J. Thomson j- suggests that in the special case of a symmetrically arranged molecule, n + 3 may be found to be proportional to the number of atoms in the molecule.
The experiments of CapstickJ have, however, shewn quite conclusively that no general law can be expected to relate 7 with the number of atoms, independently of the nature of the atoms. For instance, he finds the follow- ing values for the methane derivatives : 7 n + 3 Methane CH 4 1-313 6'4 Methyl Chloride CH 3 C1 1-279 7'2 Methylene Chloride CH 2 C1 2 T219 9'0 Chloroform CHC1 8 1154 13'0 Carbon tetrachloride CC1 4 1130 154 * Annalen der Chemie, cxtin.
What to read after The Dynamical Theory of Gases Microform?
You can find similar books in the "Read Also" column, or choose other free books by James Hopwood Jeans to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
It is, however, quite clear from experiment that for many gases the value of 7 is very much lower than 1^. In other words, the molecules of many substances must not be regarded simply as rigid bodies, for the energy of internal motion is comparable with the energies of translation and rotation.
272. Various attempts have been made to connect the values of n and 7 with the number of atoms in the molecule. Naumann*, for instance, suggested that n is identical with the number of atoms in the molec...ule, while J. J. Thomson j- suggests that in the special case of a symmetrically arranged molecule, n + 3 may be found to be proportional to the number of atoms in the molecule.
The experiments of CapstickJ have, however, shewn quite conclusively that no general law can be expected to relate 7 with the number of atoms, independently of the nature of the atoms. For instance, he finds the follow- ing values for the methane derivatives : 7 n + 3 Methane CH 4 1-313 6'4 Methyl Chloride CH 3 C1 1-279 7'2 Methylene Chloride CH 2 C1 2 T219 9'0 Chloroform CHC1 8 1154 13'0 Carbon tetrachloride CC1 4 1130 154 * Annalen der Chemie, cxtin.
What to read after The Dynamical Theory of Gases Microform?
You can find similar books in the "Read Also" column, or choose other free books by James Hopwood Jeans to read onlineMoreLess
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