The Effect of Certain Dissolved Substances On the Infra Red Absorption of Water
The Effect of Certain Dissolved Substances On the Infra Red Absorption of Water
Jacob R Jacob Roland Collins
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An example of this is shown in Fig. 2. \ V 'Wfltar __ Wove Lengths in M/crons Fig. 2. 5A r solution of NaOH. 200 grams per liter. Density 1. 186 gr. /c. C. 492 J. R. COLLINS. [SECOND [SERIES. Solutions of NaOH, KOH and LiOH were studied and curves for NaOH only are shown as they are typical of the results for all three substances. Grantham has already studied solutions of these substances in the region of the absorption at 1 . 44 /* and showed that all of them rendered the water less absorbing ...in that band in spite of an absorption band of the substances themselves which overlaps that of water. Curves A and B of Fig. 2 show the effect of NaOH on water in the bands at . 97 JJL and 1. 20 ju- At i. 20 n there is a decided increase in the transmission but at the other band there is a decrease in transmission on one side of the band. From the distorted shape of the solution curve it was suspected that the hydroxides had absorption bands near . 96/1, i. I /* and 1. 27 /JL. Concen- trated solutions were made of KOH in absolute methyl alcohol and absolute ethyl alcohol and the transmission curves determined.
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