The Effect of Substitution On the Free Energy of Reduction of Benzoquinone Incl
The Effect of Substitution On the Free Energy of Reduction of Benzoquinone Incl
Lillian Eloise Baker
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4009 5 . 2979 . 6988. . 6990 23. 65 . 4079 -. 2908 5 . 6987: Hydroquinone . 4078 5 . 2911 5 . 6990 134. 9 oxidized . 4078 5 . 2911. . 6990 . 6991 23. 65 . 4014 . 2980 . 6994 Toluquinone* . 3438 5 . 3017 5 . 6456 reduced . 3437 5 . 3017 5 . 6455 . 3471 . 2978 . 6449 . 6454 21. 84 124. 6 , 3546 5 . 2908 5 . 6455 p-Xyloquinone* . 2991 5 . 2909 . 5900. . 5900 19. 96 113. 9 reduced . 2991 . 2909 . 5900 p-Thymoquinone . 2861 5 -. 3015 5 . 5877 reduced . 2859 . 3016 . 5875 . 5876 19. 88 113. 4 Dimetho...xy- , 2231 g . 2908 5 . 5140 . 5139 17. 39 99. 2 quinone . 2229 5 -. 2908 5 . 5138 reduced Napthaquinone . 1789 5 . 2909 . 4698 5 . 4699 15. 91 90. 7 reduced . 1791 . 2909 . 4700 *The author regrets that the original article of Biilman on "L'hy- drogenation des quinhydrones" referred to by Sorensen (ref. P. 1), as "dans 1'ecret de fete ( Universitites Festskref t) " did not come to her attention through its subsequent publication in Annals re Chemie 15, 109 (1921), until after this work was ready for the press.
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