The Electrical Conductivity of Non-Aqueous Solutions ..
The Electrical Conductivity of Non-Aqueous Solutions ..
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K with the sub- script r indicates that those values were obtained by using Kudolphi's formula, while K with the subscript o indicates that Ostwald's formula was employed.
Table XXXIV.
V /: 100 iTr 100 ir( 11.4 8.28 0.82 0.242 113 17.18 0.59 0.055 1,120 27.0 0.49 0.014 3,520 29.2 0.36 0.006 It will be observed that Rudolphi's formula does not yield a constant.
From the preceding it therefore appears that neither the di- lution law of Ostwald nor that of Rudolphi holds for alcoholic solutions.
I...t has been shown from Schlamp's work that the assumption of values for ^» is not justified; therefore, since these values are wanting, the validity of the law of Ostwald and of that of Ru- dolphi cannot be tested in regard to this solvent. The data avail- able are not sufficient to draw any conclusions concerning the applicability of these laws of dilution to other alcoholic solu- tions.
Nernst ^ has called attention to the fact that solvents which have a high dielectric constant yield solutions that conduct elec- tricity.
What to read after The Electrical Conductivity of Non-Aqueous Solutions ..?
You can find similar books in the "Read Also" column, or choose other free books by Azariah Thomas Lincoln to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
K with the sub- script r indicates that those values were obtained by using Kudolphi's formula, while K with the subscript o indicates that Ostwald's formula was employed.
Table XXXIV.
V /: 100 iTr 100 ir( 11.4 8.28 0.82 0.242 113 17.18 0.59 0.055 1,120 27.0 0.49 0.014 3,520 29.2 0.36 0.006 It will be observed that Rudolphi's formula does not yield a constant.
From the preceding it therefore appears that neither the di- lution law of Ostwald nor that of Rudolphi holds for alcoholic solutions.
I...t has been shown from Schlamp's work that the assumption of values for ^» is not justified; therefore, since these values are wanting, the validity of the law of Ostwald and of that of Ru- dolphi cannot be tested in regard to this solvent. The data avail- able are not sufficient to draw any conclusions concerning the applicability of these laws of dilution to other alcoholic solu- tions.
Nernst ^ has called attention to the fact that solvents which have a high dielectric constant yield solutions that conduct elec- tricity.
What to read after The Electrical Conductivity of Non-Aqueous Solutions ..?
You can find similar books in the "Read Also" column, or choose other free books by Azariah Thomas Lincoln to read onlineMoreLess
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