The Electrolytic Determination of Manganese And Its Seperation From Zinc And Iro
The Electrolytic Determination of Manganese And Its Seperation From Zinc And Iro
George Philipp Scholl
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1007 0. 0494 5 O. IOIO O. IOIO O. IOIO 0. 1009 0. 0494 0. 0988 5 5 O. IOIO O. IOII 0. 0988 5 O. IOIO O. IOIO 0. 1007 O. IOII 0. 0988 0. 0988 5 5 Time. Temp, kat bode . Age. 4V 2 ordinary ] '. 2 4-4 5 . 2 4-4 5 . 2 44 5 . 2 4-4 4 1 /, . 2 4. 4 4 1 /. . 2 4. 4 5 . 2 4. 4 5 . 2 4-4 5 . 2 4. 4 5 . 2 4. 4 5 " ] [. 2 4. 4 It was thus establshed that the separation of iron and man- ganese could also be effected in an electrolyte, consisting mainly of formic acid. It was found, however, that though the... sodium 24 sulphite was very effective as far as the iron was concerned, it acted as a retarding agent upon the manganese, inasmuch as it was found impossible to remove the last traces of manganese in any reasonable time. When only 0. 0494 gram of manganese were present, the complete deposition could be effected in about ten to eleven hours, but thirteen or fourteen hours were needed for 0. 0988 gram of manganese. The precipitate obtained at the end of electrolysis, when all the manganese was deposited, was not adherent, though at the time when the electrode with the iron deposit on it was removed the deposit of manganese peroxide appeared adherent.
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