The Electrolytic Dissociation Theory With Some of Its Applications An Elementa

Cover The Electrolytic Dissociation Theory With Some of Its Applications An Elementa
The Electrolytic Dissociation Theory With Some of Its Applications An Elementa
Talbot, Henry Paul, 1864-1927
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Magnesium (40) Mg ++ colorless, exists in neutral and acid soln.
with OH~: a white ppt. , Mg(OH) 2, which is easily sol. In NH 4 - salts, probably because in the presence of NH 4 + the OH~-ions cannot reach a sufficient concentration to give the solubility product with Mg ++ (see Co(OH) 2 ).
with COf~ and C 2 OC~: no ppt. , if NH 4 -salts are also present.
with NH+ and PO± in ammoniacal soln. : white crystalline ppt. , MgNH 4 P0 4 .
Sodium, Potassium, and Ammonium (41) Na +, K +, NH 4 + colorle
...ss, exist in neutral, acid, or alkaline soln. ; do not form complex ions, do not form any insol. Ppts. With the common anions. K + gives with PtCl 6 __ and with Co(N0 2 ) 6 characteristic difficultly sol. Yellow ppts. , K 2 PtCl 6 and K 8 Co(N0 2 ) 6, while the corresponding Na-salts are sol. NH 4 + gives with PtCl 6 likewise a difficultly sol. Yellow ppt. , (NH 4 ) 2 PtCl 6 ; but it differs markedly from K + and Na + in that it forms with OH" the very slightly dissociated body, NH 4 OH, while the hydroxides of the other two metals are highly ionized.

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