The Electrolytic Preparation of Potassium Chloride : With Test of a Nickel-Chromium Electrode

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In neutral solution this iswoxidized by the free hypochlorous acid to chlorate, according toequation (12). In strongly alkaline solutions, however, the increased concentration of the OH decreases the con- centration of the HOCl to a very small quantity, and the formation of chlorate tak takes place only by the discharge of the CIO ions, according to equation (14).
Consequently, the only effect of the increase in concentration of the free chlorine is an increase in hypochlorite concentration.
11
... • Siuamary .
A brief accoimt of the important developments in the theory and experiment* al work on the electrolysis of the alkali chlorides is of interest at this point.
The reactions between chlorine and alkali hydrate were noted soon after the discovery of the element, but did not receive much study until recent years.
The first experiments of importance were those of Hausermann and Naschold, in 1394. The attributed the formation of chlorate to primany reaction. Oettel, in his experiments of about the same date, advanced the conclusion that the form- ation of chlorate was due in neutral sol- utions tb secondary reaction, and to primary reaction in alkaline solutions.


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