The Elements of Electro Chemistry Treated Experimentally
The Elements of Electro Chemistry Treated Experimentally
Robert Theodor Wilhelm Lpke
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M. F. Of the combination would be equal to the E. M. F. Of a cell containing the anode of one of the cells of the combination as anode and the kathode of the CHAP, v. ] THE SOLUTION-PRESSURES OF THE METALS. 165 other as kathode. The calculated value of TT for the combination of cells Zn/ZnSO 4 /CdSO 4 /Cd and Cd/CdSO 4 /CuSO 4 /Cu is TT = (-521 - -158) + (-158 + -582) = 1-103 volts ; and, as a matter of fact, the same value is found for the cell Zn/ZnSO 4 /CuSO 4 /Cu (law of the electromotive s...eries). The foregoing discussion leads us to regard a list of metals arranged in order of the values of p as the true electromotive series of these metals. Such a series is essentially chemical in its character, as the solution-pressure is a chemical constant of each metal. (If the metals are arranged in conformity with their readiness to undergo oxidation, the order is the same. ) The following electromotive series results from Neumann's estimations of the values of P : Mg, Al, Zn, Cd, Fe, Co, Ni, Pb, H, Sn, Cu, Hg, Ag, Pd, Pt, Au.
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