The Fatty Acid Radicals of Liver Lecithin

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93, H 12. 76. Found. C 75. 72, H 13. 53.
Molecular weight was 278, stearic acid had a molecular weight of 284. The substance melted at 7lC. , stearic acid melts at 70-7lC.
When this was mixed with a sample of very pure stearic acid melting at 74C. The mixture melted at 74C.
///. Bromine Addition Products of the U maturated Acids.
An attempt was made to separate and to characterize th:e individ- ual unsaturated acids by preparing the bromine addition products.
P. A. LEVENE AND H. S. SIMMS 283 40
... gm. Of pure lecithin, which had been prepared from the cadmium chloride salt as described above, were used.
No. 119.
0. 0996 gm. Of substance gave on combustion 0. 0994 gm. Of H 2 0, 0. 2768 gm. Of CO 2, and 0. 0090 gm. Of ash.
0. 1798 gm. Of substance required 2. 40 cc. Of 0. 1 N acid, corresponding to 0. 00336 gm. Of N.
0. 2697 gm. Of substance gave 0. 0390 gm. Of Mg 2 P 2 O 7 .
C 4 4H 8 7O 9 NP. Calculated. C 65. 59, H 10. 89, N 1. 74, P 3. 86. Found. C 64. 83, H 11. 16, N 1. 87, P 4. 03.
This was hydrolyzed with a 10 per cent solution of hydrochloric acid, the acids were dissolved in ether, washed with water, dried, and the ether evaporated off.


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