The Gas Phase And Surface Radiation Chemistry of Hydrogen-Carbon Monoxide Mixtures

Cover The Gas Phase And Surface Radiation Chemistry of Hydrogen-Carbon Monoxide Mixtures
The Gas Phase And Surface Radiation Chemistry of Hydrogen-Carbon Monoxide Mixtures
St. Charles, Frank Kelly, 1951-
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Also note that the G-values decrease with increasing carbon number for all three systems.
With the unpacked vessels, the yield of oxygenated products was generally larger than that of the hydrocarbon products except for methane. Alkane yields were larger than the corresponding alkenes by a factor of about 10.
With the addition of alumina, the G-values for all products were increased with the most notable increase occurring with the alkenes.
Ethylene yield was increased by a factor of lO", alkan
...e and CO2 yields were increased by a factor of about 50, and yields of oxygenated compounds increased by a factor of about 10.
121 With the Ni/AlzOs catalyst added, alkane and CO2 yields were particularly enhanced, although not simultaneously, as was shown in Chapter VI. Note that alkene yields were roughly equivalent with and without the catalyst, and that the oxygenated product yields were actually smaller with the catalyst added.
When comparing the data for the AI2O3 and Ni/AlaOs catalysts, it should be remembered that the product transfer temperature was much lower for the Ni/AlzOs catalyst than for the AI2O3 catalyst.


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