The Hydration of Normal Sodium Pyrophosphate to Orthophosphate in Varying Concen
The Hydration of Normal Sodium Pyrophosphate to Orthophosphate in Varying Concen
W C Waldemar Conrad Hansen
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425 . 500 . 500 Specific Gravity at 20 C. 1. 029 1. 029 1. 030 1. 030 1. 031 1. 031 1. 041 1. 040 1. 041 1. 041 1. 043 1. 043 1. 052 1. 052 1. 054 1. 054 1. 056 1. 056 It may be observed in the above outline that all hydra- tions were run in duplicate. In every case the two checked within experimental error and therefore the data for only one is given. All synthetic solutions for analytical curves are lettered the same as the respective solutions to be hydrated. TABLE 3. Data for Analytical Cur...ve I in Plate I. Concentration of HC1 = . 500 M. At 20 C. Temperature = 45 C. Barometric Pressure = 766. 0 mm. At 19 C. Molar Concentration Solution 1 2 3 4 5 6 of Na 4 P 2 O_ at20C. . 125 . 100 . 075 . 050 . 025 . 000 Molar Molar Concentration Concentration of Na 2 HPO 4 Voltage of Hydrogen at 20 C. E Ion X 10 2 . 000 . 2892 13. 39 . 050 . 2919 12. 14 . 100 . 2958 10. 52 . 150 . 2999 9. 06 . 200 . 3056 7. 36 . 250 . 3112 5. 99 23 Solution 1 2 3 4 5 6 Solution 1 2 3 4 5 6 Solution 1 2 3 4 5 6 TABLE 4.
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