The Physical Properties of Colloidal Solutions

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Freundlich has proved the truth of the formula for various colloids (e. G. Freundlich and Schucht, with mercury sulphide). He finds i/n to lie be- tween 0-14 and 0-20 for the various colloids studied. Paine 20 found for Bredig colloidal copper i/n to be 0-16.
Putting in the values of i/n such as those recorded, we have the resulting curve of the form illustrated in Fig. 18, from which we see that, for very small concentrations, the percentage of COAGULATION OF COLLOIDS 181 salt absorbed is very
... large, whereas for increasing concentra- tions the curve becomes asymptotic to a line parallel to the axis of concentrations. If this curve represents the absorp- tion by a given colloid of all electrolytes, irrespective of the valency of the ions, then at small concentrations of mono- valent, divalent, and trivalent absorbable ions, the number of ions absorbed by the colloid may be such that, for the mono- valent type there is absolutely no coagulative action, whereas for the divalent, or trivalent type, there may be sufficient to cause more or less rapid coagulation.

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