The Principles of Applied Electrochemistry
The Principles of Applied Electrochemistry
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, as polarisation is then very easy. As a matter of fact, these different catalysts render the depolarisation in the Bunsen cell very good, and large currents can be taken from it without any serious drop in voltage.
The E. M. F. Is about T96 volts if fuming HN0 3 be used, but with 45 per cent, to 65 per cent, acid it is 1-8-1-9 volts. This figure is composed of the difference of the anode potential difference, about 0*8 volt, and the cathode potential difference, + 1*0 to 1*1 volts. The conduc...tivities of the electrolytes are high, and the resistance conse- quently low O'l to 0'2 ohm. An objection to the cell is the evolution of nitrous fumes when working.
Poggendorff Bichromate Cell. This cell resembles the above in using a liquid depolariser, but differs from it in containing only one liquid and in dispensing with a diaphragm. The electrolyte is a solution containing H 2 S0 4 and either potassium or sodium bichromate. It of course evolves no fumes. The total reaction at the cathode can be expressed thus Cr t 7 " + 14H* > 2Cr'" + 7H 2 + 6, and that in the whole cell by 3Zn + Cr 2 0/ + HH' > 2Cr'" + 3Zn" + 7H 2 0.
What to read after The Principles of Applied Electrochemistry?
You can find similar books in the "Read Also" column, or choose other free books by Arthur John Allmand to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
, as polarisation is then very easy. As a matter of fact, these different catalysts render the depolarisation in the Bunsen cell very good, and large currents can be taken from it without any serious drop in voltage.
The E. M. F. Is about T96 volts if fuming HN0 3 be used, but with 45 per cent, to 65 per cent, acid it is 1-8-1-9 volts. This figure is composed of the difference of the anode potential difference, about 0*8 volt, and the cathode potential difference, + 1*0 to 1*1 volts. The conduc...tivities of the electrolytes are high, and the resistance conse- quently low O'l to 0'2 ohm. An objection to the cell is the evolution of nitrous fumes when working.
Poggendorff Bichromate Cell. This cell resembles the above in using a liquid depolariser, but differs from it in containing only one liquid and in dispensing with a diaphragm. The electrolyte is a solution containing H 2 S0 4 and either potassium or sodium bichromate. It of course evolves no fumes. The total reaction at the cathode can be expressed thus Cr t 7 " + 14H* > 2Cr'" + 7H 2 + 6, and that in the whole cell by 3Zn + Cr 2 0/ + HH' > 2Cr'" + 3Zn" + 7H 2 0.
What to read after The Principles of Applied Electrochemistry?
You can find similar books in the "Read Also" column, or choose other free books by Arthur John Allmand to read onlineMoreLess
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