The Principles of Mathematical Chemistry the Energetics of Chemical Phenomena

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The Principles of Mathematical Chemistry the Energetics of Chemical Phenomena
Georg Ferdinand Helm
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E. , without indices), are given by > e + c p B - s oi e - 6RIV- cJBlQR + BRIM.
122 PRINCIPLES OF MATHEMATICAL CHEMISTRY.
If instead of equation (14), page 70 (above equation (u)), we use (13), on same page, for the transformation of (15), we obtain (i 8) n^e. + ^o- s Q fr e - c p eie + RSIP + RBIC, + cje s e - C P WR + RBIP + ROIC, where C is the concentration of the constituent to which the function 71 belongs. Since C p/P (equation (9), page 69), it follows that (19) ne + c f e s e By differ
...entiation of (18) we find i. E. , with increasing concentration of a gas in a mix- ture, when the temperature does not change, the intensity of the gas increases the slower, the greater the already present concentration is.
The law, proven on page 117, of the equality of the chemical intensities of the different phases of the same substance, allows us to draw into consideration the chemical intensities of other substances that are not gaseous. We will assume any solid or liquid body that contains one constituent that is independent, which is present in the concentration C.


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