The Principles of Organic Chemistry
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When the saponification of acetoacetic ester is effected by boiling it with a dilute aqueous solution of an acid, it is probable that alcohol and acetoacetic acid are first formed: — CHaCO.CHjCOOCaHs + HOH = CH3CO.CH2COOH + CjHbOH The acid is, however, unstable under these conditions, and de- composes, yielding acetone and carbon dioxide : — CH3.CO.CH2iCOOH = CH3.CO.CH3 -I- CO2 When acetoacetic ester is hydrolyzed by boiling it with a strong aqueous solution of an alkali, or with an alcoholic s...olu- tion of potassium hydroxide, the sodium salt of acetoacetic 284 ORGANIC CHEMISTRY ester, CHsCCONa) : CH.COOC2H5, which is first formed, is hydrolyzed, in all probability, according to the equation, — CH3C(ONa):CH.COOC2H6 + NaOH = CH3C(0Na):CH.C00Na + CaHsOH In the presence of the strong alkali, the salt undergoes decompo- sition as the result of the addition of water at the double bond, and two molecules of sodium acetate are formed : — CH3.C:CH.C00Na + H2O = CH3.CO + CHaCOONa I I ONa ONa The derivatives of acetoacetic ester undergo decompositions similar to those of the ester itself.
What to read after The Principles of Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by James Flack Norris to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
When the saponification of acetoacetic ester is effected by boiling it with a dilute aqueous solution of an acid, it is probable that alcohol and acetoacetic acid are first formed: — CHaCO.CHjCOOCaHs + HOH = CH3CO.CH2COOH + CjHbOH The acid is, however, unstable under these conditions, and de- composes, yielding acetone and carbon dioxide : — CH3.CO.CH2iCOOH = CH3.CO.CH3 -I- CO2 When acetoacetic ester is hydrolyzed by boiling it with a strong aqueous solution of an alkali, or with an alcoholic s...olu- tion of potassium hydroxide, the sodium salt of acetoacetic 284 ORGANIC CHEMISTRY ester, CHsCCONa) : CH.COOC2H5, which is first formed, is hydrolyzed, in all probability, according to the equation, — CH3C(ONa):CH.COOC2H6 + NaOH = CH3C(0Na):CH.C00Na + CaHsOH In the presence of the strong alkali, the salt undergoes decompo- sition as the result of the addition of water at the double bond, and two molecules of sodium acetate are formed : — CH3.C:CH.C00Na + H2O = CH3.CO + CHaCOONa I I ONa ONa The derivatives of acetoacetic ester undergo decompositions similar to those of the ester itself.
What to read after The Principles of Organic Chemistry?
You can find similar books in the "Read Also" column, or choose other free books by James Flack Norris to read onlineMoreLess
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