The Principles of Theoretical Chemistry With Special Reference to the Constitu
The Principles of Theoretical Chemistry With Special Reference to the Constitu
Ira Remsen
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Is obtained. Only these two cases are possible. But, again, this secondary alcohol is prepared by allow- ing nascent hydrogen to act upon acetone. It will be shown that acetone must be represented by the formula CH 3 CO. Now, in its conversion into secondary propyl alcohol CH 3 acetone takes up two atoms of hydrogen, and the only place where these hydrogen atoms can find entrance into the above molecule, if the carbon is quadrivalent, is in combination with the central carbon atom. If the oxyge...n 144 PRINCIPLES OF THEORETICAL CHEMISTRY. atom is linked to the carbon atom, as in carbon monoxide, a condition which is represented by the formula C = O, we can conceive of the relation between the carbon and oxygen being changed by the action of hydrogen, so that a group HC O H may be formed. This is what is believed to take place. This addition of hydrogen changes the relation between the carbon and the oxygen and saturates them : C H CH II + I - O H OH Similar considerations, in connection with other second- ary alcohols, lead to similar results, and hence the conclu- sion is drawn that all secondary alcohols contain the group CH.
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