The Principles of Thermodynamics

Cover The Principles of Thermodynamics
The Principles of Thermodynamics
George Birtwistle
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Dissociation. Planck^ constructed the ^ function for a gas mixture. For a mol of gas the internal energy = cj, + h, where h is a constant.
Therefore for the mixture and = Swj c, „ log ^ + i2 log — : + Ki and pv = {rii + n^ + ... ) Rt.
:. 1 = E -t is a function of t, p only.
Thus C is expressed as a function oit, p, ni, n^, This is a fundamental equation of the Gibbs l, f, p, mj, W2, ... Type (§ 103) from which aU the thermodynamic 1 Wied. Ami. 1883, 120 GAS MIXTURES properties of the
... homogeneous gas mixture can be found. Planck proceeds to use the ^ function, with its minimum property, to find a formula from which the state of chemical dissociation of a gaseous substance can be deter- mined for any given temperature and pressure.
123. Thermodynamics of dilute solutions.
Planck 1 found a I, function of the same form for dilute solutions.


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