The Structure of Maltose And Its Oxidation Products With Alkaline Peroxide of Hy
The Structure of Maltose And Its Oxidation Products With Alkaline Peroxide of Hy
Siegel a Buckborough
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Dextrose hydrate (90. 90 anhydrous) was refluxed on the boiling water bath ten hours with 500 cc. Of 5% sulfuric acid. The solution darkened and showed a final content of 80. 12 g. Of anhydrous dextrose (91. 43 g. Hydrated) or a loss of 8. 56%. The solution was now adjusted so that a few drops gave the slightest precipitate with a 2% solution of sulfuric acid, filtered and concentrated 1 J. Am. Chem. Soc. , 28, 663; 29, 541. II to about 1500 cc. To remove the dextrose, the solution was heated i...n a boiling water bath with 60 g. Of calcium carbonate for ten hours and filtered. The filtrate was of a golden red color and syrupy odor. Thirty- eight grams of calcium carbonate were filtered off and digested with 5% acetic acid. An insoluble residue was left which was dissolved in hydro- chloric acid and reprecipitated with ammonia several times until per- fectly white. This gave 0. 3047 g. Of calcium oxalate. When dried to a constant weight at 100 and analyzed the following result was obtained: 0.
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