The Structure of Maltose And Its Oxidation Products With Alkaline Peroxide of Hy

Cover The Structure of Maltose And Its Oxidation Products With Alkaline Peroxide of Hy
The Structure of Maltose And Its Oxidation Products With Alkaline Peroxide of Hy
Siegel a Buckborough
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Dextrose hydrate (90. 90 anhydrous) was refluxed on the boiling water bath ten hours with 500 cc. Of 5% sulfuric acid. The solution darkened and showed a final content of 80. 12 g. Of anhydrous dextrose (91. 43 g. Hydrated) or a loss of 8. 56%.
The solution was now adjusted so that a few drops gave the slightest precipitate with a 2% solution of sulfuric acid, filtered and concentrated 1 J. Am. Chem. Soc. , 28, 663; 29, 541.
II to about 1500 cc. To remove the dextrose, the solution was heated i
...n a boiling water bath with 60 g. Of calcium carbonate for ten hours and filtered. The filtrate was of a golden red color and syrupy odor. Thirty- eight grams of calcium carbonate were filtered off and digested with 5% acetic acid. An insoluble residue was left which was dissolved in hydro- chloric acid and reprecipitated with ammonia several times until per- fectly white. This gave 0. 3047 g. Of calcium oxalate. When dried to a constant weight at 100 and analyzed the following result was obtained: 0.

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