The Study of Chemical Composition. An Account of Its Method And Historical Development, With Illustrative Quotations

Cover The Study of Chemical Composition. An Account of Its Method And Historical Development, With Illustrative Quotations
The Study of Chemical Composition. An Account of Its Method And Historical Development, With Illustrative Quotations
Ida Freund
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.101* 19' 0-7817 : 1 : 06408 KMnO4»...103* r ...101* 40' 07949 : 1 : 0-6476 Fig. 79.
1 Mitflcherlioh, Poggend, Annal., 12, 1828 (p. 138).
> Mitsoherlioh, ibid., 25, 1832 (p. 293).
* The two isomorphoas salts shoold be consistently represented alike, either by the single or the doable formulae ; by KCIO4 and EMUO4, or by Kfi\0^ and EsMn^Og. But whilst the perchlorate is always written KCIO4, hoth permanganate formulae are met with. The formula KMn04 is in agreement with the resalts of molecular
...weight determinations by the lowering of the solidification point of a non -dissociating solvent.
27—2 420 Crystalline Farm & Chemical Composition [chap.
2. Mitscherlich's recognition of the isomorphism with potas- sium sulphate of the green potassium salt of a manganese acid, and of the isomorphism with potassium perchlorat^ a. Formula of the red potassium salt of another manganese for manganic tii n ^ acid. acid, has revealed the true composition of these two acids.
" The green crystals are maoganate of potassium, which is isomorphous with the sulphate of potassium.


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